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- W2067123456 abstract "A bis-urea and a bis-thiourea host, both derived in only one step from 1,3-bis(aminomethyl)benzene, are shown to bind dihydrogenphosphate selectively over various other anions (H2PO4− > CH3COO− > Cl− > HSO4− > NO3− > ClO4−). The much stronger binding of H2PO4− by the bis-thiourea is rationalized by the stronger H-bond donor strength of the thiourea groups and the binding selectivity is explained in terms of the complex geometry and the basicity of the guest anions. The lack of self-association and the changes in the UV spectrum upon complexation make bis-thiourea hosts a promising new class of neutral receptors for dihydrogenphosphate." @default.
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- W2067123456 date "1995-09-01" @default.
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- W2067123456 title "Anion recognition by urea and thiourea groups: Remarkably simple neutral receptors for dihydrogenphosphate" @default.
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- W2067123456 doi "https://doi.org/10.1016/0040-4039(95)01296-t" @default.
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