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- W2067160937 abstract "The complex originally reported to be ‘Cr12O12(pivalate)15’ has been examined by a number of spectroscopic techniques in order to elucidate the chromium valence states. By charge balance arguments, the complex could, for example, contain nine Cr(III) and three Cr(IV) centers, contain 11 Cr(III) and one Cr(VI) center or could possess three protons, not detected by X-ray crystallography, and 12 Cr(III) centers. While a recent neutron diffraction study has suggested the existence of three additional and disordered deuterons (and thus 12 Cr(III) centers), the complex has been studied by several complementary spectroscopic techniques which confirm the formula to be Cr12O9(OH)3(pivalate)15." @default.
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- W2067160937 date "2002-01-01" @default.
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- W2067160937 title "Spectroscopic studies of the dodecanuclear chromium complex Cr12O9(OH)3(pivalate)15: confirmation of the presence of twelve Cr(III) centers and the crystal structure of Cr12O9(OH)3(pivalate)15·2PrOH·9H2O" @default.
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- W2067160937 doi "https://doi.org/10.1016/s0277-5387(01)00955-x" @default.
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