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- W2067208781 abstract "Abstract Six natural crystals from the Sludyanka crystalline complex belonging to the eskolaite (Cr 2 O 3 )–karelianite (V 2 O 3 )–hematite (Fe 2 O 3 ) solid solution were studied by means of X-ray diffraction and electron microprobe. The Fe 3+ -poor samples show a general increase in a and c cell parameters with increasing mean cationic radius (MCR), consistent with that shown by the synthetic crystals along the eskolaite–karelianite join. The Fe 3+ -richer sample deviates significantly from the behaviour shown by the Fe 3+ -poor ones, similar to synthetic and natural hematites; with increasing MCR, the a and c cell parameters increase linearly along the eskolaite-karelianite join. However, for the samples rich in Fe 3+ , from karelianite to hematite, a shows a slightly steeper slope whereas the c parameter decreases strongly. The octahedral distortion increases slightly as a function of MCR along the eskolaite-karelianite join, whereas it increases markedly for Fe 3+ -rich samples. The evolution of the octahedral edges and of the octahedral distortions as a function of MCR are responsible for the behaviour of the unit-cell parameters along the eskolaite-karelianite-hematite join." @default.
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- W2067208781 date "2008-06-01" @default.
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- W2067208781 title "Crystal-chemical study of <i>R</i><i>c</i> natural oxides along the eskolaite – karelianite – hematite (Cr<sub>2</sub>O<sub>3</sub>–V<sub>2</sub>O<sub>3</sub>–Fe<sub>2</sub>O<sub>3</sub>) join" @default.
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- W2067208781 doi "https://doi.org/10.1180/minmag.2008.072.3.785" @default.
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