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• W2067240333 abstract "The Et(3)N-assisted addition of beta-ketoester 3 to MVK in chloroform is catalyzed with high turnover efficiency by the phenyl-substituted uranyl-salophen compound 2b but not by the parent compound 1b. A plausible mechanism is suggested, involving concomitant nucleophilic attack at the beta-carbon and hydrogen bonding between the Et(3)NH(+) countercation and the carbonyl oxygen of the s-cis conformation of the enone reactant. The role of the van der Waals interactions with the aromatic side arm of 2b as a crucial driving force for catalysis is discussed." @default.
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• W2067240333 date "2008-11-11" @default.
• W2067240333 modified "2023-10-16" @default.
• W2067240333 title "The Role of Attractive van der Waals Forces in the Catalysis of Michael Addition by a Phenyl Decorated Uranyl-Salophen Complex" @default.
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• W2067240333 doi "https://doi.org/10.1021/jo801714m" @default.
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