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- W2067253874 abstract "Abstract Synthesis and characterization of a series of square planar Pt(II)-phenylpyridazine complexes are reported. The complexes have the general structure of (C–N)Pt(O–O), where HC–N is 3-phenyl-pyridazine (ppdz), 3-(3′-trifluoromethylphenyl)pyridazine (3′tfmppdz), 3-(3′-methoxyphenyl)-pyridazine (3′meoppdz), 3-(4′-methoxyphenyl)pyridazine (4′meoppdz), or 3-phenyl-6-chloro-pyridazine (6Clppdz) and HO–O is acetylacetone (Hacac). Reaction of K 2 PtCl 4 with a HC–N ligand forms the dimer, (C–N)Pt(μ-Cl) 2 Pt(C–N), which is cleaved with Hacac to give the corresponding monomer, (C–N)Pt(O–O). The emission characteristics of these complexes are governed by the substituents of the cyclometalating ligands, showing emission λ max values from 508 to 610 nm. Strong spin-orbit coupling of the platinum atom allows for the formally forbidden mixing of the 1 MLCT with the 3 MCLT and 3 ( π – π *) states." @default.
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- W2067253874 date "2004-01-01" @default.
- W2067253874 modified "2023-09-27" @default.
- W2067253874 title "Synthesis and characterization of phosphorescent platinum complexes containing phenylpyridazine" @default.
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- W2067253874 doi "https://doi.org/10.1016/j.msec.2003.09.024" @default.
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