Matches in SemOpenAlex for { <https://semopenalex.org/work/W2067256831> ?p ?o ?g. }
- W2067256831 endingPage "16270" @default.
- W2067256831 startingPage "16265" @default.
- W2067256831 abstract "We describe polymersomes with ionic liquid interiors dispersed in water. The vesicles are prepared via a simple and spontaneous migration of poly(butadiene-b-ethylene oxide) (PB-PEO) block copolymer vesicles from a hydrophobic ionic liquid, 1-ethyl-3-methylimidazolium bis(trifluoromethylsulfonyl)imide ([EMIM][TFSI]), to water at room temperature. As PB is insoluble in both water and [EMIM][TFSI] and PEO is well solvated in both media, the vesicles feature a PB membrane with PEO brushes forming both interior and exterior coronas. The robust and stable PB-PEO vesicles migrate across the liquid-liquid interface with their ionic liquid interiors intact and form a stabilized aqueous dispersion of vesicles enclosing microscopic ionic liquid pools. The nanostructure of the vesicles with ionic liquid interiors dispersed in water is characterized by direct visualization using cryogenic transmission electron microscopy. Upon heating, the vesicles can be quantitatively transferred back to [EMIM][TFSI], thus enabling facile recovery. The reversible transport capability of the shuttle system is demonstrated by the use of distinct hydrophobic dyes, which are selectively and simultaneously loaded in the vesicle membrane and interior. Furthermore, the fluorescence of the loaded dyes in the vesicles enables probing of the microenvironment of the vesicular ionic liquid interior through solvatochromism and direct imaging of the vesicles using laser scanning confocal microscopy. This vesicle system is of particular interest as a nanocarrier or nanoreactor for reactions, catalysis, and separations using ionic liquids." @default.
- W2067256831 created "2016-06-24" @default.
- W2067256831 creator A5021121847 @default.
- W2067256831 creator A5029326074 @default.
- W2067256831 date "2010-10-21" @default.
- W2067256831 modified "2023-09-25" @default.
- W2067256831 title "Polymersomes with Ionic Liquid Interiors Dispersed in Water" @default.
- W2067256831 cites W1600292521 @default.
- W2067256831 cites W1965487190 @default.
- W2067256831 cites W1966010330 @default.
- W2067256831 cites W1967366094 @default.
- W2067256831 cites W1972886627 @default.
- W2067256831 cites W1974688481 @default.
- W2067256831 cites W1976483646 @default.
- W2067256831 cites W1977572346 @default.
- W2067256831 cites W1977665107 @default.
- W2067256831 cites W1979463458 @default.
- W2067256831 cites W1982143279 @default.
- W2067256831 cites W1982318942 @default.
- W2067256831 cites W1983940429 @default.
- W2067256831 cites W1984130749 @default.
- W2067256831 cites W1986293276 @default.
- W2067256831 cites W1986352004 @default.
- W2067256831 cites W1987171888 @default.
- W2067256831 cites W1988260329 @default.
- W2067256831 cites W1991336810 @default.
- W2067256831 cites W1991495276 @default.
- W2067256831 cites W1993964194 @default.
- W2067256831 cites W1996827376 @default.
- W2067256831 cites W1999393639 @default.
- W2067256831 cites W2000291025 @default.
- W2067256831 cites W2002730188 @default.
- W2067256831 cites W2010977079 @default.
- W2067256831 cites W2013175804 @default.
- W2067256831 cites W2013232612 @default.
- W2067256831 cites W2021181435 @default.
- W2067256831 cites W2021908094 @default.
- W2067256831 cites W2025247704 @default.
- W2067256831 cites W2025454146 @default.
- W2067256831 cites W2028106947 @default.
- W2067256831 cites W2029644100 @default.
- W2067256831 cites W2030498396 @default.
- W2067256831 cites W2030901654 @default.
- W2067256831 cites W2033297392 @default.
- W2067256831 cites W2034033759 @default.
- W2067256831 cites W2036697585 @default.
- W2067256831 cites W2039326248 @default.
- W2067256831 cites W2040430014 @default.
- W2067256831 cites W2042509700 @default.
- W2067256831 cites W2045678504 @default.
- W2067256831 cites W2046607191 @default.
- W2067256831 cites W2049622924 @default.
- W2067256831 cites W2050053874 @default.
- W2067256831 cites W2051894601 @default.
- W2067256831 cites W2052068549 @default.
- W2067256831 cites W2052341407 @default.
- W2067256831 cites W2054467687 @default.
- W2067256831 cites W2054689720 @default.
- W2067256831 cites W2057529776 @default.
- W2067256831 cites W2058852920 @default.
- W2067256831 cites W2060200790 @default.
- W2067256831 cites W2067091714 @default.
- W2067256831 cites W2067151250 @default.
- W2067256831 cites W2069111085 @default.
- W2067256831 cites W2069520354 @default.
- W2067256831 cites W2071615814 @default.
- W2067256831 cites W2074074629 @default.
- W2067256831 cites W2074143219 @default.
- W2067256831 cites W2074370738 @default.
- W2067256831 cites W2075108470 @default.
- W2067256831 cites W2083851164 @default.
- W2067256831 cites W2084993698 @default.
- W2067256831 cites W2087262433 @default.
- W2067256831 cites W2087835260 @default.
- W2067256831 cites W2092565027 @default.
- W2067256831 cites W2105035967 @default.
- W2067256831 cites W2105544332 @default.
- W2067256831 cites W2109239812 @default.
- W2067256831 cites W2115036661 @default.
- W2067256831 cites W2118885385 @default.
- W2067256831 cites W2126852238 @default.
- W2067256831 cites W2136616023 @default.
- W2067256831 cites W2140168656 @default.
- W2067256831 cites W2140170994 @default.
- W2067256831 cites W2144699874 @default.
- W2067256831 cites W2146988816 @default.
- W2067256831 cites W2147095826 @default.
- W2067256831 cites W2163097494 @default.
- W2067256831 cites W2169777848 @default.
- W2067256831 cites W2170955296 @default.
- W2067256831 cites W2171193481 @default.
- W2067256831 cites W2171376065 @default.
- W2067256831 cites W3023319571 @default.
- W2067256831 cites W4212814362 @default.
- W2067256831 cites W4241409678 @default.
- W2067256831 cites W4246239401 @default.
- W2067256831 cites W4252529934 @default.
- W2067256831 doi "https://doi.org/10.1021/ja107751k" @default.