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- W2067262806 abstract "Shape memory properties of polymers represent one of the most expanding fields in polymer science related to numerous smart applications. Recently, multiple-shape memory polymers (multiple-SMPs) have attracted significant attention and can be achieved with complex polymer architectures. Here, miscible PLLA/PMMA blends with broad glass transitions are investigated as an alternative platform to design multiple-SMPs. Dual-shape memory experiments were first conducted at different stretching temperatures to identify the so-called “temperature memory effect”. The switch temperature of the symmetric 50% PLLA/50% PMMA blend smoothly shifted from 70 to 90 °C for stretching temperatures increasing from 65 to 94 °C, attesting for a significant “temperature memory effect”. Asymmetric formulations with 30% and 80% PMMA also present a “temperature memory effect”, but the symmetric blend clearly appeared as the most efficient formulation for multiple-shape memory applications. A programming step designed with two succe..." @default.
- W2067262806 created "2016-06-24" @default.
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- W2067262806 date "2014-09-17" @default.
- W2067262806 modified "2023-10-14" @default.
- W2067262806 title "Designing Multiple-Shape Memory Polymers with Miscible Polymer Blends: Evidence and Origins of a Triple-Shape Memory Effect for Miscible PLLA/PMMA Blends" @default.
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- W2067262806 doi "https://doi.org/10.1021/ma500846x" @default.
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