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- W2067276032 abstract "ThalliumI ions can be titrated accurately in a strong hydrochloric acid medium with potassium dichromate standard solution. The reaction was first examined by potentiometric titration. Siloxene proved to be suitable as a chemiluminescent indicator for detection of the end-point, emitting an orange-red chemiluminescence as soon as the titrant is present in excess. Thallium(I) ionen können in stark salzsaurer Lösung mit Kaliumdichromat genau titriert werden. Die Reaktion Wurde mittels potentiometrischer Titration untersucht. Siloxen war ein geeigneter Chemiluminescensindicator der orangefarbenes Licht aussendet, wenn das Titrationsmittel im Überschuss anwesend ist. Les ions thallium(I) peuvent être dosés avec précision en milieu acide chlorhydrique fort par une solution étalon de bichromate de potassium. La réaction a d'abord été étudiée par potentiométrie. Le siloxéne convient comme indicateur chimiluminescent pour la détermination du point équivalent. Il émet en effet une lumière rouge orangée lorsque le réactif titrant est en excès." @default.
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- W2067276032 date "1963-05-01" @default.
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- W2067276032 title "Titration of thalliumI ions with a chemiluminescent end-point" @default.
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- W2067276032 doi "https://doi.org/10.1016/0039-9140(63)80053-3" @default.
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