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• W2067321344 abstract "We report the discovery of a second, higher-Tc superconducting organic charge-transfer salt derived from the electron-donor molecule BEDT-TTF (or ET), the novel organometallic anion [Cu(CF3)4]−, and the neutral solvent molecule 1, 1, 2-trichloroethane (TCE). We have very recently reported that this charge-transfer system yields a new superconducting ϰ phase salt, ϰL- (ET)2Cu(CF3)4·TCE, with inductive onset Tcrmc=4.0 K at ambient pressure. This ϰ phase salt (ϰ denotes a particular packing arrangement of the ET organic donor molecules) is electrocrystallized in the habit of hexagonal plates. Crystals possessing a needle-like habit electrocrystallize simultaneously with these plates, and we find these needles to be a distinctly different superconducting phase with diamagnetic onset Tc=9.2±0.1 K at ambient pressure. On the basis of our experiments, we denote this new superconducting phase as ϰH−(ET)2Cu(CF3)4·(TCE)x,X<1." @default.
• W2067321344 created "2016-06-24" @default.
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• W2067321344 date "1994-09-01" @default.
• W2067321344 modified "2023-10-01" @default.
• W2067321344 title "A new 9 K superconducting organic salt composed of the bis (ethylenedithio) tetrathiafulvalene (ET) electron-donor molecule and the tetrakis (trifluoromethyl) cuprate (III) anion, [Cu(CF3)4]-" @default.
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• W2067321344 doi "https://doi.org/10.1016/0921-4534(94)90854-0" @default.
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