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- W2067337117 abstract "An ethylene-vinyl acetate copolymer (EVA) was chemically modified by the introduction of pendent thiol groups (EVA-SH) suitable for chain transfer. The resulting copolymer was grafted with 4-phenylazophenyl 4-(4-acryloyloxybutoxy)benzoate, a liquid crystalline monomer (LCM), initiated by AIBN. Grafting was performed at LCM/EVA-SH mass ratios of 10, 5, 2 and 1 in the feed. The grafting degree, i.e., the fraction of LC polymer in the graft copolymer, ranged from ca. 5-30 wt.-%. The thermal transitions were investigated by DSC, pointing at marked microphase separation between LC and polyethylene moieties. The anisotropic properties of the graft copolymers were confirmed by cross-polarized light microscopy. All the samples showed birefringence at 140°C, some only on shearing however." @default.
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- W2067337117 date "1996-07-01" @default.
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- W2067337117 title "Polyethylene graft copolymers with a liquid crystalline component in the side chains" @default.
- W2067337117 doi "https://doi.org/10.1002/macp.1996.021970703" @default.
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