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- W2067348550 abstract "Kinetic solvent effects on hydrogen-atom abstraction from N,N-diethylhydroxylamine and N,N-dibenzylhydroxylamine by the 2,2-diphenyl-1-picrylhydrazyl radical (DPPH˙) indicated that these compounds are much weaker hydrogen-bond donors than implied by the currently accepted αH2 value of 0.453. Lower αH2 values were also obtained by monitoring 1 ∶ 1 complex formation with two strong hydrogen-bond acceptors, HMPA and DMSO, in tetrachloromethane using IR spectroscopy. It is concluded that the αH2 value for sterically non-hindered N,N-dialkylhydroxylamines should be revised downward to 0.29." @default.
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- W2067348550 date "2001-01-01" @default.
- W2067348550 modified "2023-09-25" @default.
- W2067348550 title "Revision of the αH2 value for N,N-dialkylhydroxylamines based on kinetic and spectroscopic measurements" @default.
- W2067348550 cites W2009907465 @default.
- W2067348550 doi "https://doi.org/10.1039/b102247o" @default.
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