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• W2067351057 abstract "Irradiation of rhodium(II) azido complex [Rh(N3){N(CHCHPtBu2)2}] allowed for the spectroscopic characterization of the first reported rhodium complex with a terminal nitrido ligand. DFT computations reveal that the unpaired electron of rhodium(IV) nitride complex [Rh(N){N(CHCHPtBu2)2}] is located in an antibonding Rh-N π* bond involving the nitrido moiety, thus resulting in predominant N-radical character, in turn providing a rationale for its transient nature and observed nitride coupling to dinitrogen." @default.
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• W2067351057 date "2013-11-18" @default.
• W2067351057 modified "2023-10-18" @default.
• W2067351057 title "Synthesis and Reactivity of a Transient, Terminal Nitrido Complex of Rhodium" @default.
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• W2067351057 doi "https://doi.org/10.1021/ja409764j" @default.
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