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- W2067352209 abstract "This report describes the electrical conductivity measurements for metal sulfides containing Be, Mg, Ca, and Sr in group IIa and Sc and Y in group IIIa. To avoid contamination, preparations of sulfide disks were strictly controlled. All the group IIa metal sulfides showed predominantly ionic conduction. Comparison of the measured activation energies for these metal sulfides with those for other alkaline-earth sulfides and oxides indicated that the predominant charge carriers were the metal cations in these ionically conductive sulfides. At higher pressures, the conductivities of MgS and BeS were linearly dependent on the sulfur partial pressure showing a slope of 1/6 on a logarithmicplots. This indicates that these sulfides are p-type electrical conductors in that pressure range. A theoretical analysis showed that fully ionized metal vacancies are the predominant defects. For Sc 2 S 3 and Y 2 S 3 , thisslope was -3/16, indicating predominance of scandium and yttrium interstitial ions. At higher pressures, Y 2 S 3 also showed a +3/16 dependence, indicating p-type conduction due to fully ionized yttrium vacancies." @default.
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- W2067352209 date "1995-01-01" @default.
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- W2067352209 title "Sulfur Pressure Dependence of Electrical Conductivity of Group IIa and IIIa Metal Sulfides" @default.
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- W2067352209 doi "https://doi.org/10.2320/matertrans1989.36.1263" @default.
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