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- W2067363921 abstract "Cadmium fluorochloride glass (CdFCl) is considered as a more favorable host for Pr 3+ 1 G 4 - 3 H 5 transition than all-fluoride hosts, but it cannot be drawn easily into fibers. This critical problem is largely correlated with its special devitrification behavior and temperature dependence of viscosity. The high Avrami coefficients of crystallization obtained by isothermal method (n>4) and by non-isothermal method (n=4) suggest that nucleation rate increases during the crystallization. Meanwhile Avrami coefficients (n) and activation energy (E) values vary with the crystalline fraction(x). This corresponds to the formation of different phases during crystallization. The thermal XRD measurements performed from 210 to 320 °C confirm that chlorine-rich phases appear first at low temperature while the fluoride phases form lately. Comparison with fluorozirconate glass (ZBLAN) shows that CdFCl glass has a lower logη - T slope. As a result the drawing temperature of the CdFCl glass is well above Tg, in the crystallization thermal range. These two factors explain the difficulties encountered in drawing CdFCl fibers from a preform. Drawing fibers directly from the melt should be an alternative method for CdFCl glasses." @default.
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- W2067363921 date "1998-09-28" @default.
- W2067363921 modified "2023-09-25" @default.
- W2067363921 title "Critical problem of cadmium fluorochloride glass fiber drawing" @default.
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- W2067363921 doi "https://doi.org/10.1117/12.323397" @default.
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