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- W2067370858 abstract "Abstract Concept of the “wall-loss constant” used for the description of particle deposition on the container walls is criticised. Kinetics of simultaneous Brownian coagulation and diffusive deposition of monodisperse particles in a stagnant fluid contained in the spherical vessel are investigated. Assuming that the rate of coagulation and deposition are additive the differential equation is obtained whose solution describes the decay with time of the total particle concentration in the initial stage of the coagulation-deposition process. The results obtained are used for another checking of the concept of the “wall-loss constant”. It is concluded that even in this most simple case this concept is unrealistic. Furthermore the results obtained support the old idea that neglecting the wall losses may be one of the main reasons of the discrepancy between the experimental and theoretical values of the coagulation constant. Possible application of the results obtained in the theory and operation of static diffusion batteries is briefly discussed. The developed approach can be applied to containers of arbitrary geometrical shapes." @default.
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- W2067370858 date "1977-01-01" @default.
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- W2067370858 title "Simultaneous brownian coagulation and diffusive deposition of monodisperse particles" @default.
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- W2067370858 doi "https://doi.org/10.1016/0004-6981(77)90028-2" @default.
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