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• W2067376413 abstract "The conductivity and permittivity of sodium kaolinite are measured with respect to frequency (10–105 Hz), concentration (0.1 to 100 g solid per 100 ml sample), and temperature (293–318°K). The Stern/Gouy model of the colloid double layer is applied, together with the Schwarz theory for polarization due to bound surface ions. The total surface change on kaolinite, as in the preceding paper on swelling clays, is quantitatively accounted for by the combined conductivity and permittivity results. An edge-to-edge (EE) and edge-to-face (EF) associated structure made up of face-to-face (FF) aggregates of multilayer clay platelets is indicated, with microscopic dimensions similar to the individual particle sizes, though much smaller than is suggested by the macroscopic sedimentation rates. The macroscopic structure is probably closer to a microporous “honeycomb” than a macroporous “capillary” system. The conductivity results and mechanisms are applied to electrophoresis and electroosmosis, and the permittivity results and mechanisms are correlated with dielectrophoresis. The problem of electrokinetic dewatering in both swelling and nonswelling clays is discussed, referring to the results of the accompanying paper on swelling clays." @default.
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• W2067376413 date "1980-04-01" @default.
• W2067376413 modified "2023-10-18" @default.
• W2067376413 title "Electrical properties and the surface characteristics and structure of clays. II. Kaolinite—a nonswelling clay" @default.
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• W2067376413 doi "https://doi.org/10.1016/0021-9797(80)90221-0" @default.
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