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• W2067454566 abstract "Two new redox active ligands based on di(2-(3-organopyrazolyl)-p-tolyl)amine have been prepared in order to investigate potential effects of steric bulk on the structures, electronic properties, or reactivity of tricarbonylrhenium(I) complexes. Replacing the hydrogens at the 3-pyrazolyl positions with alkyl groups causes significant distortion to the ligand framework due to potential interactions between these groups when bound to a fac-Re(CO)3 moiety. The distortions effectively increase the nucleophilic character of the central amino nitrogen and ligand-centered reactivity of the metal complexes." @default.
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• W2067454566 date "2011-01-01" @default.
• W2067454566 modified "2023-09-28" @default.
• W2067454566 title "Using sterics to promote reactivity in fac-Re(CO)3 complexes of some ‘non-innocent’ NNN-pincer ligands" @default.
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• W2067454566 doi "https://doi.org/10.1039/c1dt10030k" @default.
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