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- W2067501325 abstract "Abstract The rotational barriers in axially chiral quinolin-2-one and quinazolin-2-one possessing N -( ortho - tert -butyl)phenyl group were found to significantly increase in comparison with those of corresponding dihydroquinolin-2-one and dihydroquinazolin-2-one. Analysis of transition state structure during N–Ar bond rotation based on DFT calculation indicates that the increase in the rotational barrier is due to considerable distortion of the nitrogen-containing heterocyclic part." @default.
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- W2067501325 date "2012-08-01" @default.
- W2067501325 modified "2023-10-01" @default.
- W2067501325 title "Studies on rotational barriers of N–C axially chiral compounds: increase in the rotational barrier by aromatization" @default.
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- W2067501325 doi "https://doi.org/10.1016/j.tetlet.2012.06.007" @default.
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