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- W2067503460 abstract "The reactivity of copper—cerium intermetallic compounds, which are known precursors for highly active, low temperature methanol synthesis catalysts, has been studied by temperature programmed oxidation. Oxidation profiles in air, nitrous oxide-nitrogen, carbon monoxide and synthesis gas for CeCu2 and CeCu6 are compared with those of the constituent elements and related to in situ X-ray diffraction observations. For the cerium—rich alloy, oxidation of the rare earth component does not proceed to completion at ambient pressure and hydrogen exposure is shown to be crucial for the efficient activation of the alloys under the mild conditions necessary for the generation of a highly active catalyst." @default.
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- W2067503460 date "1988-01-01" @default.
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- W2067503460 title "Activation of copper—cerium intermetallic catalyst precursors by temperature-programmed oxidation" @default.
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- W2067503460 doi "https://doi.org/10.1016/s0166-9834(00)80767-8" @default.
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