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• W2067563240 abstract "Abstract A series of osmium( VI ) nitride complexes containing 8‐quinolinolato ligands, [Os VI (N)(X‐Q) 2 Cl] (X = H, 5‐Cl, 5‐NO 2 , 2‐Me; 1a – d ), have been synthesized by reaction of HX‐Q with [ n Bu 4 N][Os VI (N)Cl 4 ] in the presence of 2,6‐dimethylpyridine. The ν(Os≡N) stretches of these compounds occur at 1056–1075 cm –1 , and are within the range (1050–1120 cm –1 ) found for most osmium nitride species. The structure of 1d has been determined by X‐ray crystallography. The osmium center adopts a distorted octahedral geometry, and the two quinolinolato ligands are cis to each other. The three N atoms are in a facial arrangement, and the Os≡N bond distance is 1.644(6) Å. Complex 1c readily reacts with the carbene precursors bis(1,3‐dialkylimidazolidin‐2‐ylidene) (L R 2 ; R = Me, Et, or CH 2 Ph) to produce the osmium( IV ) azavinylidene species, [Os IV (N=L R )(NO 2 ‐Q) 2 Cl], which are derived from the formal addition of the carbenes L R to Os VI ≡N. The structure of [Os IV (N=L Et )(NO 2 ‐Q) 2 Cl] ( 2b ) has been determined by X‐ray crystallography. The osmium center has a distorted octahedral geometry in which the facial arrangement of the three N atoms is retained. The Os(1)–N(5) distance of 1.875(6) Å is rather long and, together with the rather acute Os(1)–N(5)–C(19) angle of 133.8(5)°, indicates that there is no significant multiple‐bond character in the Os(1)–N(5) bond. (© Wiley‐VCH Verlag GmbH & Co. KGaA, 69451 Weinheim, Germany, 2005)" @default.
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• W2067563240 date "2005-02-01" @default.
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• W2067563240 title "Addition of Carbenes to an Osmium( <scp>VI</scp> ) Nitride Complex" @default.
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• W2067563240 doi "https://doi.org/10.1002/ejic.200400539" @default.
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