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- W2067583957 abstract "A new family of isostructural Mn-Ln heterometallic clusters, [Mn(II)(2)Mn(III)(2)Ln(III)(2)(Piv)(8)(thme)(2)(H(2)tea)(2)] (H(3)thme = 1,1,1-tris(hydroxymethyl)ethane, Hpiv = pivalic acid, H(3)tea = triethanolamine, and Ln = Pr, Nd, Sm, Eu, Gd, Tb, and Dy) have been prepared by reaction of the hexanuclear manganese precursor, [Mn(6)O(2)(Piv)(10)(4-Me-Py)(2.5)(Hpiv)(1.5)], with H(3)thme, H(3)tea, and Ln(NO(3))(3)·6H(2)O under the solvothermal conditions. Complexes 1Pr-7Dy were characterized by single-crystal X-ray diffraction and their core [Mn(2)(III)Mn(2)(II)Ln(2)(III)(μ(3)-OR)(4)(μ(2)-OR)(6)](6+) composed of four face-sharing defected cubane units. Antiferromagnetic (AF) exchange interactions were suggested for all of the complexes by solid-state dc magnetic susceptibility measurements. Complexes 6Tb and 7Dy, show frequency-dependent ac susceptibility signals suggestive of slow magnetic relaxation." @default.
- W2067583957 created "2016-06-24" @default.
- W2067583957 creator A5008138946 @default.
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- W2067583957 creator A5036731471 @default.
- W2067583957 creator A5068299889 @default.
- W2067583957 creator A5091199854 @default.
- W2067583957 date "2013-01-01" @default.
- W2067583957 modified "2023-10-06" @default.
- W2067583957 title "Syntheses, structures and magnetic properties of a family of heterometallic [Mn<sup>II</sup><sub>2</sub>Mn<sup>III</sup><sub>2</sub>Ln<sup>III</sup><sub>2</sub>] clusters" @default.
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