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- W2067672068 abstract "Abstract 2-Methylbenzoxazole can be lithiated at the methyl group to give a dimer (6) which reacts with various-element halides (PhBCl2, Ph2SnCl2, Me2SiCl2) to give the new chelate complexes (7). Reaction of 6 with two equivalents of (E)-2-(chloro)dimethylstannyl-3-diethylboryl-2-pentene yields a new polycyclic compound (8) which contains five-coordinate tin (a chiral centre), and four-coordinate boron. No dimer corresponding to 6 was obtained when 2-methylbenzothiazole was lithiated. The new compounds have been characterized by 1H, 11B, 13C, 29Si, 119Sn NMR spectroscopy and by elemental analyses." @default.
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- W2067672068 date "1987-09-01" @default.
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- W2067672068 title "Lithiierung von 2-Methylbenzoxazol: organometallische Derivate eines neuen dreizähnigen Liganden" @default.
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- W2067672068 doi "https://doi.org/10.1016/0022-328x(87)85119-7" @default.
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