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• W2067683246 abstract "The average rate of configuration transition of the (dAT) copolymer has been determined by the study of the spectrum of light scattering. For the alkaline transition of (dAT) at 18.7°C, pH = 11.0, and ionic strength of 0.1M Na+, we find a rate τR−1 = 2.33 ± 0.21 × 103sec−1. This compares favorably with previous measurements obtained by the temperature-jump technique. Simultaneously, we have measured the linear diffusion coefficient within the transition region to be D = 2.91 ± 0.14 × 10−8cm2/sec. There is a 6%–10% variation of the diffusion rates between the samples at the low-pH (10.4) helical conformation and at the high-pH(11.6) random coil conformation." @default.
• W2067683246 created "2016-06-24" @default.
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• W2067683246 date "1970-06-15" @default.
• W2067683246 modified "2023-10-03" @default.
• W2067683246 title "Experimental Study of Reaction Kinetics by Light Scattering. II. Helix–Coil Transition of the Copolymer Deoxyadenylate–Deoxythymidylate (dAT)" @default.
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• W2067683246 doi "https://doi.org/10.1063/1.1672930" @default.
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