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- W2067687939 abstract "Abstract The electrochemical reduction peaks previously observed at about —0.4 V vs. SCE in the case of chloro- or bromo-silanes and -germanes actually refer to reduction of HCl or HBr formed by hydrolysis arising from traces of water in the solvent. This hydrolysis is catalysed by nucleophilic solvents. The electrochemical reduction of halo-silanes and -germanes in aprotic solvents giving the corresponding disilanes and digermanes is shown to be an irreversible process taking place at a low potential (—2 to —2.5 V vs. SCE)." @default.
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- W2067687939 date "1980-02-01" @default.
- W2067687939 modified "2023-10-17" @default.
- W2067687939 title "A re-examination of the electrochemical reduction of halosilanes and halogermanes" @default.
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- W2067687939 doi "https://doi.org/10.1016/s0022-328x(00)93814-2" @default.
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