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- W2067689927 abstract "Abstract Ferrocene derivatives have found many different uses and applications in organometallic chemistry, material chemistry, and catalysis. We have shown that using a catalytic amount (5–10 mol‐%) of commercially available indium tribromide, at room temperature, many carbon nucleophiles, such as indoles, allylsilane, enolsilane, silyl ketene acetal, diketone, and trimethylsilylcyanide, smoothly react with different optically active ferrocenyl alcohol derivatives to afford the desired products in high yield, with retention of configuration. Also, many different N‐nucleophiles (azide, carbamates) and O‐nucleophiles (alcohols) react as well, again with retention of configuration. (© Wiley‐VCH Verlag GmbH & Co. KGaA, 69451 Weinheim, Germany, 2007)" @default.
- W2067689927 created "2016-06-24" @default.
- W2067689927 creator A5073614830 @default.
- W2067689927 creator A5077044727 @default.
- W2067689927 date "2007-04-16" @default.
- W2067689927 modified "2023-09-24" @default.
- W2067689927 title "Facile Access to Optically Active Ferrocenyl Derivatives with Direct Substitution of the Hydroxy Group Catalyzed by Indium Tribromide" @default.
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- W2067689927 doi "https://doi.org/10.1002/ejoc.200700146" @default.
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