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• W2067701498 abstract "Recent spacecraft observations of Venus permit a detailed model of sulfur chemistry in the atmosphere-lithosphere system. Pioneer Venus experiments confirm that, as predicted, COS and H2S are dominant over SO2 in the lower atmosphere, and that the equilibrium concentrations of S2 and S3 are significant. Many criteria serve to bracket the oxidation state of the crust: it is nearly certain that the S22−/SO42− buffer regulates the oxygen fucagity, and that FeO is at least as abundant as Fe2O3 in crustal silicates. A highly oxidized crust (as, for example, would result from O2 absorption complementary to escape of vast amounts of H2) is incompatible with the gas-phase sulfur chemistry. If the Pioneer Venus mass spectrometer estimates of the abundance of sulfur gases are correct, Earth-like models for the bulk composition of Venus are seriously in error, and a far lower FeO content is required for Venus." @default.
• W2067701498 created "2016-06-24" @default.
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• W2067701498 date "1980-06-01" @default.
• W2067701498 modified "2023-09-26" @default.
• W2067701498 title "Oxidation state of the atmosphere and crust of Venus from pioneer Venus results" @default.
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• W2067701498 doi "https://doi.org/10.1016/0019-1035(80)90098-6" @default.
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