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- W2067785450 abstract "Abstract The role of basic interactions (i.e. electrondashelectron, iondashion and electrondashion) on the energetics of undercooled ( T ⪡ T m ) liquid metallic system has been investigated within the firsts-principle approach to pseudopotential perturbation theory and the Gibbs-Bogoliaubov variational method. Its application is made to Na and T -dependence of internal energies, interatomic pair potentials, entropies and heat capacities are obtained in the region T ⪡ T m . Various entropic contributions in the undercooled region decrease much faster than the enthalpic terms. Heat capacities calculated both from entropy and enthalpy terms increase with decreasing T in the undercooled region, and exhibit anomalous behaviour at a temperature which is interpreted as glass transition temperature." @default.
- W2067785450 created "2016-06-24" @default.
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- W2067785450 date "1997-09-01" @default.
- W2067785450 modified "2023-10-01" @default.
- W2067785450 title "Energetics of undercooled liquid metals" @default.
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- W2067785450 doi "https://doi.org/10.1016/s0921-4526(97)00419-5" @default.
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