Matches in SemOpenAlex for { <https://semopenalex.org/work/W2067840707> ?p ?o ?g. }
- W2067840707 endingPage "6116" @default.
- W2067840707 startingPage "6107" @default.
- W2067840707 abstract "The changes in the dynamic structure during temperature-induced phase transition in D2O/ethanol solutions of poly(vinyl methyl ether) (PVME) were studied using NMR methods. The effect of polymer concentration and ethanol (EtOH) content in D2O/EtOH mixtures on the appearance and extent of the phase separation was determined. Measurements of 1H and 13C spin–spin and spin–lattice relaxations showed the presence of two kinds of EtOH molecules: besides the free EtOH expelled from the PVME mesoglobules there are also EtOH molecules bound in PVME mesoglobules. The existence of two different types of EtOH molecules at temperatures above the phase transition was in solutions with polymer concentration 20 wt% manifested by two well-resolved NMR signals (corresponding to free and bound EtOH) in 13C and 1H NMR spectra. With time the originally bound EtOH is slowly released from globular-like structures. From the point of view of polymer–solvent interactions in the phase-separated PVME solutions both EtOH and water (HDO) molecules show a similar behaviour so indicating that the decisive factor in this behaviour is a polar character of these molecules and hydrogen bonding." @default.
- W2067840707 created "2016-06-24" @default.
- W2067840707 creator A5009056879 @default.
- W2067840707 creator A5031172109 @default.
- W2067840707 creator A5074350830 @default.
- W2067840707 date "2006-08-01" @default.
- W2067840707 modified "2023-09-23" @default.
- W2067840707 title "NMR study of temperature-induced phase separation and polymer–solvent interactions in poly(vinyl methyl ether)/D2O/ethanol solutions" @default.
- W2067840707 cites W1966297896 @default.
- W2067840707 cites W1982400649 @default.
- W2067840707 cites W1985639203 @default.
- W2067840707 cites W1988007994 @default.
- W2067840707 cites W2001575435 @default.
- W2067840707 cites W2006241468 @default.
- W2067840707 cites W2013678264 @default.
- W2067840707 cites W2018692212 @default.
- W2067840707 cites W2023788720 @default.
- W2067840707 cites W2024760922 @default.
- W2067840707 cites W2026905237 @default.
- W2067840707 cites W2027350310 @default.
- W2067840707 cites W2037874072 @default.
- W2067840707 cites W2049925529 @default.
- W2067840707 cites W2052372217 @default.
- W2067840707 cites W2055391316 @default.
- W2067840707 cites W2069731034 @default.
- W2067840707 cites W2082900882 @default.
- W2067840707 cites W2085712370 @default.
- W2067840707 cites W2089814066 @default.
- W2067840707 cites W2090803827 @default.
- W2067840707 cites W2102470041 @default.
- W2067840707 cites W2106594445 @default.
- W2067840707 cites W2109357036 @default.
- W2067840707 cites W2314547305 @default.
- W2067840707 cites W2463097112 @default.
- W2067840707 doi "https://doi.org/10.1016/j.polymer.2006.06.061" @default.
- W2067840707 hasPublicationYear "2006" @default.
- W2067840707 type Work @default.
- W2067840707 sameAs 2067840707 @default.
- W2067840707 citedByCount "37" @default.
- W2067840707 countsByYear W20678407072012 @default.
- W2067840707 countsByYear W20678407072013 @default.
- W2067840707 countsByYear W20678407072014 @default.
- W2067840707 countsByYear W20678407072015 @default.
- W2067840707 countsByYear W20678407072016 @default.
- W2067840707 countsByYear W20678407072017 @default.
- W2067840707 countsByYear W20678407072018 @default.
- W2067840707 countsByYear W20678407072019 @default.
- W2067840707 countsByYear W20678407072020 @default.
- W2067840707 countsByYear W20678407072021 @default.
- W2067840707 countsByYear W20678407072022 @default.
- W2067840707 crossrefType "journal-article" @default.
- W2067840707 hasAuthorship W2067840707A5009056879 @default.
- W2067840707 hasAuthorship W2067840707A5031172109 @default.
- W2067840707 hasAuthorship W2067840707A5074350830 @default.
- W2067840707 hasConcept C103319777 @default.
- W2067840707 hasConcept C112887158 @default.
- W2067840707 hasConcept C147789679 @default.
- W2067840707 hasConcept C15920480 @default.
- W2067840707 hasConcept C163111631 @default.
- W2067840707 hasConcept C178790620 @default.
- W2067840707 hasConcept C185592680 @default.
- W2067840707 hasConcept C188027245 @default.
- W2067840707 hasConcept C188109995 @default.
- W2067840707 hasConcept C2780407432 @default.
- W2067840707 hasConcept C2780471494 @default.
- W2067840707 hasConcept C32909587 @default.
- W2067840707 hasConcept C44280652 @default.
- W2067840707 hasConcept C521977710 @default.
- W2067840707 hasConceptScore W2067840707C103319777 @default.
- W2067840707 hasConceptScore W2067840707C112887158 @default.
- W2067840707 hasConceptScore W2067840707C147789679 @default.
- W2067840707 hasConceptScore W2067840707C15920480 @default.
- W2067840707 hasConceptScore W2067840707C163111631 @default.
- W2067840707 hasConceptScore W2067840707C178790620 @default.
- W2067840707 hasConceptScore W2067840707C185592680 @default.
- W2067840707 hasConceptScore W2067840707C188027245 @default.
- W2067840707 hasConceptScore W2067840707C188109995 @default.
- W2067840707 hasConceptScore W2067840707C2780407432 @default.
- W2067840707 hasConceptScore W2067840707C2780471494 @default.
- W2067840707 hasConceptScore W2067840707C32909587 @default.
- W2067840707 hasConceptScore W2067840707C44280652 @default.
- W2067840707 hasConceptScore W2067840707C521977710 @default.
- W2067840707 hasIssue "17" @default.
- W2067840707 hasLocation W20678407071 @default.
- W2067840707 hasOpenAccess W2067840707 @default.
- W2067840707 hasPrimaryLocation W20678407071 @default.
- W2067840707 hasRelatedWork W1978452520 @default.
- W2067840707 hasRelatedWork W2000707149 @default.
- W2067840707 hasRelatedWork W2011854874 @default.
- W2067840707 hasRelatedWork W2053837780 @default.
- W2067840707 hasRelatedWork W2066970497 @default.
- W2067840707 hasRelatedWork W2089723006 @default.
- W2067840707 hasRelatedWork W2756982567 @default.
- W2067840707 hasRelatedWork W4242455819 @default.
- W2067840707 hasRelatedWork W169495349 @default.
- W2067840707 hasRelatedWork W2128065966 @default.
- W2067840707 hasVolume "47" @default.
- W2067840707 isParatext "false" @default.