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- W2067849073 abstract "Syntheses of the title diols, their acetates, and their methyl ethers are described, where the aryl group is p-chloro-p-methoxy-, p-methylthio-, and 2,4-dinitro-phenyl. Rearrangement through an episulphonium ion-pair occurs in the preparation of a dimethanesulphonate from 2-(p-methoxyphenylthio)propane-1,3-diol, the product being the derivative of the isomeric 1,2-diol. Unrearranged dimethanesulphonates were obtained from all the other diols, but the 1,3-dimethanesulphonates where the aryl group is phenyl, p-chlorophenyl, and p-methylthiophenyl undergo rearrangement to the 1,2-isomers in boiling acetone. In methanol, solvolysis of the 1,3-dimethanesulphonates occurs much more rapidly than with the 1,2 isomers." @default.
- W2067849073 created "2016-06-24" @default.
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- W2067849073 date "1971-01-01" @default.
- W2067849073 modified "2023-09-25" @default.
- W2067849073 title "Cytotoxic compounds. Part XII. Some 3-arylthiopropane-1,2-diols and 2-arylthiopropane-1,3-diols. Rearrangement of the 1,3-dimethanesulphonates to the 1,2-isomers" @default.
- W2067849073 doi "https://doi.org/10.1039/j39710001442" @default.
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