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- W2067857274 abstract "Ti4O7 has two transitions with decreasing temperature and the structure has been refined in each phase. The triclinic structure (Al) consists of rutile-like layers of TiO6 octahedra extending indefinitely in the a-b plane and four octahedra thick along the c axis. The average TiO distances for the four independent Ti atoms are 2.006(2), 2.006(2), 2.004(2), and 2.018(2) Å at 298K; 2.011(4), 2.000(4), 2.015(4), and 2.012(4) Å at 140K; 2.043(4), 1.973(4), 2.044(4), and 1.996(4) Å at 120K. At 120K there is a clear separation into strings of Ti3+ or Ti4+ ions running parallel to the pseudorutile c axis. In addition the 3+ sites are paired to form short TiTi bonds, whereas the Ti4+ atoms are displaced toward one oxygen giving short TiO distances of 1.776(4) and 1.787(4) Å and thus forming a zig-zag chain. In the intermediate phase the interatomic distances are only slightly different from those at 298K but the thermal factors are anomalously large." @default.
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- W2067857274 date "1973-02-01" @default.
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- W2067857274 title "Structural aspects of the metal-insulator transitions in Ti4O7" @default.
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- W2067857274 doi "https://doi.org/10.1016/0022-4596(73)90184-9" @default.
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