FRINK Linked Data Fragments server

Matches in SemOpenAlex for { <https://semopenalex.org/work/W2067859093> ?p ?o ?g. }

• W2067859093 endingPage "433" @default.
• W2067859093 startingPage "423" @default.
• W2067859093 abstract "The 193 nm photodissociation of azomethane CH3N2CH3→CH3+N2+NH3 has been investigated by photofragment translational spectroscopy. The time-of-flight (TOF) distribution of the CH3 photogragments consists of a single and relatively narrow peak which indicates that the two methyl radicals are formed with equal or very similar velocity distributions. Based on this result and on the observed TOF distribution of the N2 fragment, the rupture of the two CN bonds is shown to be consistent with a concerted mechanism with the possibility of a symmetric three-body decay. Furthermore, the concerted mechanism implies that dissociation is preceded by rapid isomerisation from the initial trans form to a gauche or cis type structure. The isotropic (β≈0) angular distributions of CH3 and N2 are consistent with an electronic transition moment being oriented parallel to the NN bond." @default.
• W2067859093 created "2016-06-24" @default.
• W2067859093 creator A5012449365 @default.
• W2067859093 creator A5054945697 @default.
• W2067859093 creator A5057960044 @default.
• W2067859093 date "1995-06-01" @default.
• W2067859093 modified "2023-09-26" @default.
• W2067859093 title "The concerted photodissociation of azomethane at 193 nm" @default.
• W2067859093 cites W1966880143 @default.
• W2067859093 cites W1973897972 @default.
• W2067859093 cites W1976207511 @default.
• W2067859093 cites W1977820375 @default.
• W2067859093 cites W1979352811 @default.
• W2067859093 cites W1984277579 @default.
• W2067859093 cites W1992339397 @default.
• W2067859093 cites W1996253176 @default.
• W2067859093 cites W1996625756 @default.
• W2067859093 cites W1998112755 @default.
• W2067859093 cites W2014075855 @default.
• W2067859093 cites W2015400565 @default.
• W2067859093 cites W2015518413 @default.
• W2067859093 cites W2022324327 @default.
• W2067859093 cites W2026203538 @default.
• W2067859093 cites W2028414692 @default.
• W2067859093 cites W2028457664 @default.
• W2067859093 cites W2031885363 @default.
• W2067859093 cites W2036007249 @default.
• W2067859093 cites W2038527810 @default.
• W2067859093 cites W2039042515 @default.
• W2067859093 cites W2051243321 @default.
• W2067859093 cites W2053141832 @default.
• W2067859093 cites W2056440114 @default.
• W2067859093 cites W2057402107 @default.
• W2067859093 cites W2062569152 @default.
• W2067859093 cites W2066158746 @default.
• W2067859093 cites W2074404321 @default.
• W2067859093 cites W2077842864 @default.
• W2067859093 cites W2080415163 @default.
• W2067859093 cites W2082697836 @default.
• W2067859093 cites W2084358538 @default.
• W2067859093 cites W2089410683 @default.
• W2067859093 cites W2324739151 @default.
• W2067859093 cites W2507579122 @default.
• W2067859093 cites W2950089106 @default.
• W2067859093 cites W2950884861 @default.
• W2067859093 cites W2951460967 @default.
• W2067859093 cites W2951798653 @default.
• W2067859093 cites W3033880797 @default.
• W2067859093 cites W4249695563 @default.
• W2067859093 doi "https://doi.org/10.1016/0301-0104(95)00070-5" @default.
• W2067859093 hasPublicationYear "1995" @default.
• W2067859093 type Work @default.
• W2067859093 sameAs 2067859093 @default.
• W2067859093 citedByCount "15" @default.
• W2067859093 countsByYear W20678590932012 @default.
• W2067859093 countsByYear W20678590932018 @default.
• W2067859093 crossrefType "journal-article" @default.
• W2067859093 hasAuthorship W2067859093A5012449365 @default.
• W2067859093 hasAuthorship W2067859093A5054945697 @default.
• W2067859093 hasAuthorship W2067859093A5057960044 @default.
• W2067859093 hasConcept C102931765 @default.
• W2067859093 hasConcept C121332964 @default.
• W2067859093 hasConcept C126661725 @default.
• W2067859093 hasConcept C139066938 @default.
• W2067859093 hasConcept C147597530 @default.
• W2067859093 hasConcept C147789679 @default.
• W2067859093 hasConcept C161790260 @default.
• W2067859093 hasConcept C178790620 @default.
• W2067859093 hasConcept C184050105 @default.
• W2067859093 hasConcept C185592680 @default.
• W2067859093 hasConcept C29135686 @default.
• W2067859093 hasConcept C32891209 @default.
• W2067859093 hasConcept C41999313 @default.
• W2067859093 hasConcept C54582936 @default.
• W2067859093 hasConcept C55493867 @default.
• W2067859093 hasConcept C62520636 @default.
• W2067859093 hasConcept C71240020 @default.
• W2067859093 hasConcept C75079739 @default.
• W2067859093 hasConcept C75473681 @default.
• W2067859093 hasConceptScore W2067859093C102931765 @default.
• W2067859093 hasConceptScore W2067859093C121332964 @default.
• W2067859093 hasConceptScore W2067859093C126661725 @default.
• W2067859093 hasConceptScore W2067859093C139066938 @default.
• W2067859093 hasConceptScore W2067859093C147597530 @default.
• W2067859093 hasConceptScore W2067859093C147789679 @default.
• W2067859093 hasConceptScore W2067859093C161790260 @default.
• W2067859093 hasConceptScore W2067859093C178790620 @default.
• W2067859093 hasConceptScore W2067859093C184050105 @default.
• W2067859093 hasConceptScore W2067859093C185592680 @default.
• W2067859093 hasConceptScore W2067859093C29135686 @default.
• W2067859093 hasConceptScore W2067859093C32891209 @default.
• W2067859093 hasConceptScore W2067859093C41999313 @default.
• W2067859093 hasConceptScore W2067859093C54582936 @default.
• W2067859093 hasConceptScore W2067859093C55493867 @default.
• W2067859093 hasConceptScore W2067859093C62520636 @default.
• W2067859093 hasConceptScore W2067859093C71240020 @default.
• W2067859093 hasConceptScore W2067859093C75079739 @default.
• W2067859093 hasConceptScore W2067859093C75473681 @default.

• next