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- W2067884920 abstract "Abstract The kinetics of disproportionation reaction of hexafluoroacetylacetonate-copper(I)-cycloocta-1,5-diene [(hfac)Cu I (COD)] was investigated by the use of differential scanning calorimetry (DSC) with different heating rates in dynamic nitrogen atmosphere. First, the activation energies ( E a s) of the disproportionation reaction were estimated with model-free isoconversional methods, respectively. The E a s were found to fall within the range between 17.6 and 18.7 kJ mol −1 , with no temperature and heating rate effects observed. Then, when the E a was ascertained, the model-fitting methods with least square fitting procedure were adopted to determine the kinetic model for the disproportionation reaction. As a result, the disproportionation reaction follows second-order reaction kinetics." @default.
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- W2067884920 date "2007-05-01" @default.
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- W2067884920 title "A DSC study on the kinetics of disproportionation reaction of (hfac)CuI(COD)" @default.
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- W2067884920 doi "https://doi.org/10.1016/j.tca.2007.01.007" @default.
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