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- W2067898045 abstract "Aryl- and alkylphosphines R3P, R2PF, R2PCl, and RPCl2 are oxidized by IF5 to the corresponding fluorophosphoranes in a fast one step-reaction at or below 0°C. The only co- product is elemental iodine. IF3 or IF as reduction products of IF5 are not observed. Fission of PC-bonds by <IF& from I2 and IF5 is negligible under reaction conditions. In alkylfluorophosphoranes fluoride donor-acceptor- interactions between fluorophosphoranes and IF5 are observed." @default.
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- W2067898045 date "1986-11-01" @default.
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- W2067898045 title "Beiträge zur chemie des iodpentafluorids Teil IV. IF5 ein selektives oxidatives fluorierungs-mittel für organophosphor(III)-verbindungen" @default.
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- W2067898045 doi "https://doi.org/10.1016/s0022-1139(00)81928-4" @default.
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