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• W2067932652 abstract "Abstract Unit-cell parameters of La 3 Nb 0.5 Ga 5.5 O 14 (langanite) have been determined at a number of pressures up to 23GPa in diamond anvil high pressure cells with single crystal X-ray diffraction techniques. The anisotropic behaviour of unit cell parameters of langanite is caused by differences of bonding strength in direction parallel to the a - and c -axis. Within the investigated pressure range, the c / a -ratio increases from 0.6232 to 0.6503. The volume compressibility of trigonal langanite (space group P 321) is the 0.007 GPa -1 , with calculated bulk modulus of 145(3)GPa (B' 0 =1.4(8)). At a pressure of 12.4(3)GPa a first-order phase transition was detected, characterised by a discontinuity in the pressure dependence of lattice parameter c . The high-pressure phase (presumably monoclinic, A 2) with a volume compressibility of 0.011 GPa -1 (B 0 =93(2) GPa, B' 0 =1.9(9)) is more compressible as compared to the initial phase due to an abnormal pressure dependence of lattice parameter a ." @default.
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• W2067932652 date "2002-05-01" @default.
• W2067932652 modified "2023-09-23" @default.
• W2067932652 title "Influence of high hydrostatic pressure on lattice parameters of a single crystal of La3Nb0.5Ga5.5O14" @default.
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• W2067932652 doi "https://doi.org/10.1524/zkri.217.5.212.20637" @default.
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