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• W2067967098 startingPage "5020" @default.
• W2067967098 abstract "Abstract The accurate prediction of electrokinetic migration velocity and dispersion is crucial to separating electrophoretically charged solutes in micro‐ or nanochannels. In this paper, we investigate numerically the influence of transverse electromigration (TEM) on the solute electrokinetic transport in a series of micro‐ and nanochannels. The TEM, often ignored in previous studies, is demonstrated to significantly affect the solute migration velocity in nanochannels and the electrokinetic dispersion in microchannels. This is because the TEM can force either positively charged solutes into or negatively charged solutes out of the electrical double layer that forms adjacent to the negatively charged channel wall and contains the velocity gradients. Analytical solutions are also derived for characterizing the electrokinetic transport of charged solutes in nanochannels, which has been validated to be in good agreement with the numerical simulation. Moreover, we demonstrate that the proposed analytical formula for the solute migration velocity actually applies to channels of any size." @default.
• W2067967098 created "2016-06-24" @default.
• W2067967098 creator A5022411269 @default.
• W2067967098 creator A5022713992 @default.
• W2067967098 date "2006-12-01" @default.
• W2067967098 modified "2023-10-15" @default.
• W2067967098 title "Electrokinetic transport of charged solutes in micro- and nanochannels: The influence of transverse electromigration" @default.
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• W2067967098 doi "https://doi.org/10.1002/elps.200600031" @default.
• W2067967098 hasPubMedId "https://pubmed.ncbi.nlm.nih.gov/17124708" @default.
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