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- W2068003067 abstract "Abstract On the basis of our previous results, where optimal conditions for the lipase‐catalyzed hydrolysis of sunflower oil in a high‐pressure batch stirred tank reactor were determined, some thermodynamic and kinetic properties of lipase preparation Lipolase 100T ( Aspergillus niger lipase) were established. Activation energy (32.7 kJ/mol) was determined from an Arrhenius plot. Activity of the Lipolase 100T increased between 35 and 50°C, but with further temperature increase thermal deactivation occurred. The thermal deactivation rate constant was 0.40, and the deactivation enthalpy was 123.0 kJ/mol. Because of the desirability of continuous applications of enzyme‐catalyzed reactions, a high‐pressure continuous flat‐shape membrane reactor (HP CFSMR) was designed. Hydrolysis of sunflower oil in this reactor was performed. Maximal conversion in the HP CFSMR was achieved after 1 h. A polysulfone membrane was successfully used as a separation unit, and the highest conversion of FFA was determined at 50°C, 200 bar, and a flow rate for substrates of 0.1 mL/min (each)." @default.
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- W2068003067 date "2003-08-01" @default.
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- W2068003067 title "Thermodynamic properties of the enzymatic hydrolysis of sunflower oil in high-pressure reactors" @default.
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- W2068003067 doi "https://doi.org/10.1007/s11746-003-0772-3" @default.
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