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- W2068005135 abstract "Thermogravimetry and electrical conductivity were used to study the oxidation of surface Cr3+-ions and of bulk Fe2+-ions of several spinels from 100 to 700°C. Below about 300°C, Cr3+-ions at octahedral sites are found to be oxidized only on the surface and the resulting change in conductivity may be attributed to the constantly increasing charge carrier concentration arising from the presence of Cr3+ and Cr4+-ions. At higher temperatures, the weight gain change and the profile of the σ = f(T) curves can be explained in terms of the bulk oxidation of Fe3+ ions at tetrahedral sites." @default.
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- W2068005135 date "1987-10-01" @default.
- W2068005135 modified "2023-09-25" @default.
- W2068005135 title "Study by electrical conductivity and thermogravimetry of oxidation of some spinels with Cr3+ and Fe2+-ions" @default.
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- W2068005135 doi "https://doi.org/10.1016/0254-0584(87)90118-0" @default.
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