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- W2068012732 abstract "Abstract A one‐pot reaction of copper powder and nickel and ammonium acetates in a CH 3 OH solution of ethylenediamine (en) yields a unique 1D aqua‐bridged polymer [Cu(en) 2 (μ 2 ‐H 2 O) 2 Ni(OAc) 4 ] n · 4 n H 2 O ( 1 ) with an ambidentate Ni(OAc) 4 2– fragment that has not been previously characterized. The basic structural motif of 1 contains a previously unreported heterometallic M(μ 2 ‐H 2 O)M′ aqua‐bridge chain with alternating metal atoms. A complex system of N/O–H ··· O hydrogen bonds strengthens the polymeric chains and links them into a supramolecular three‐dimensional network. Variable‐temperature magnetic susceptibility measurements of 1 revealed a weak ferromagnetic coupling ( J = 1.1 cm –1 ) between the paramagnetic copper(II) and nickel(II) ions, which is transmitted through the oxygen bridges." @default.
- W2068012732 created "2016-06-24" @default.
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- W2068012732 date "2010-07-27" @default.
- W2068012732 modified "2023-09-23" @default.
- W2068012732 title "A CuIINiII Complex with Ethylenediamine: Crystal Structure and Ferromagnetic Behaviour of an Aqua-Bridged Heterometallic Chain Containing Ambidentate Ni(OAc)42- Blocks" @default.
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- W2068012732 doi "https://doi.org/10.1002/ejic.201000212" @default.
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