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- W2068018105 abstract "Abstract Three different {η 5 ‐(+)‐neomenthylcyclopentadienyl}ruthenium complexes have been synthesized from (−)‐menthol: [(η 6 ‐benzene){η 5 ‐(+)‐neomenthylcyclopentadienyl}ruthenium( II )] hexafluorophosphate ( 1 ), [tris(acetonitrile){η 5 ‐(+)‐neomenthylcyclopentadienyl}ruthenium( II )] hexafluorophosphate ( 2 ) and [(η 6 ‐cyclooctatetraene){η 5 ‐(+)‐neomenthylcyclopentadienyl}ruthenium( II )] hexafluorophosphate ( 3 ). X‐ray structural determination (space group P 2 1 2 1 2 1 ) and NMR spectroscopic studies of 3 show it exists as a single stereoisomer in both the solid and solution phase, with [α] 20 D = +92.5. The chiral modification of the Cp ligand induces anisochrony for all of the magnetically active nuclei of the unsubstituted COT ligand. (© Wiley‐VCH Verlag GmbH & Co KGaA, 69451 Weinheim, Germany, 2003)" @default.
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- W2068018105 date "2003-01-01" @default.
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- W2068018105 title "[(η <sup>6</sup> ‐Cyclooctatetraene){η <sup>5</sup> ‐(+)‐neomenthylcyclopentadienyl}ruthenium( <scp>II</scp> )] Hexafluorophosphate: Synthesis and Characterization of a Chiral Mixed Sandwich Complex" @default.
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- W2068018105 doi "https://doi.org/10.1002/ejic.200390042" @default.
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