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• W2068034251 abstract "The nonionic surfactant hexa(ethylene glycol) mono-n-dodecyl ether (C12EO6) self-assembles in aqueous solutions to form small globular micelles. Progressive substitution of C12EO6 by a telechelic polymer (a water soluble poly(ethylene oxide) (PEO) chain grafted at both extremities with hydrophobic C12H 25 chains (PEO-2m)) is shown to preserve the initial C12 hydrophobic cores, at least up to 10 polymers per hydrophobic core, but to introduce additional interactions between the micelles. At low micellar concentrations (∼ <0.03 M) these interactions are attractive, leading to a phase separation even with a minute substitution of C12EO6 by the polymer while at higher concentrations even a minute substitution leads to an effective repulsive interaction. These observations are discussed in terms of a competition between bridging and decoration of the micelles." @default.
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• W2068034251 date "1998-07-11" @default.
• W2068034251 modified "2023-09-25" @default.
• W2068034251 title "Interactions between Nonionic Surfactant Micelles Introduced by a Telechelic Polymer. A Small Angle Neutron Scattering Study" @default.
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• W2068034251 doi "https://doi.org/10.1021/la9712395" @default.
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