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- W2068051668 abstract "Two water soluble Re(I) tricarbonyl diimine complexes containing cationic 2,2′-bipyridyl ligands [Re(L1)(CO)3(AN)]2+ (1) and [Re(L2)(CO)3(AN)]3+ (2) (L1 and L2: a cationic 2,2′-bipyridyl ligand, AN: acetonitrile) were synthesized and characterized. Their photophysical, electrochemical and electrochemiluminescent properties were investigated. The crystal structures of the two complexes have also been determined. Electrochemiluminescence (ECL) of the two complexes 1 and 2 have been studied in aqueous buffer solution in the presence of co-reactant tri-n-propylamine (TPrA) or 2-(dibutylamino)ethanol (DBAE) at a Au working electrode. The ECL behavior of the complexes was also studied in the presence of several surfactants such as Triton X-100 and Zonyl FSN. The ECL signals of the rhenium(I) complex were enhanced about 190-fold and 70-fold at a Au electrode in the presence of Triton X-100 for the [Re(L1)(CO)3(AN)]2+/TPrA and [Re(L1)(CO)3(AN)]2+/DBAE systems, respectively." @default.
- W2068051668 created "2016-06-24" @default.
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- W2068051668 date "2012-01-01" @default.
- W2068051668 modified "2023-09-27" @default.
- W2068051668 title "Synthesis, structure, photophysics and electrochemiluminescence of Re(i) tricarbonyl complexes with cationic 2,2-bipyridyl ligands" @default.
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- W2068051668 doi "https://doi.org/10.1039/c2dt30074e" @default.
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