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• W2068065756 abstract "The v=0–57 levels of the 3p+3p doubly excited 1 3∑−g state of Na2 have been observed by pulsed perturbation facilitated optical–optical double resonance (PFOODR) fluorescence excitation spectroscopy. The Tv=57=39 943.5 cm−1 of the 1 3∑−g state is 385 cm−1 above the X 2∑+g v+=0, J+=0 ionization threshold and 9 cm−1 below the Na (3p,2P3/2)+Na(3p,2P1/2) dissociation limit. No significant line broadening was observed above the X 2∑+g v+=0, J+=0 ionization threshold with our resolution. Molecular constants and the Rydberg–Klein–Rees (RKR) potential curve have been obtained from the observed data. The major constants are Te=36 519.13(17) cm−1, ωe=93.635(41) cm−1, and Be=0.118 95(90) cm−1. We have carried out an all-electron ab initio calculation for the 1 3∑−g state and transition dipole moment for the 1 3∑−g↔b 3Πu system of Na2. Molecular constants calculated from our ab initio potential curve have reasonable agreement with the experimental constants." @default.
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• W2068065756 date "1995-11-01" @default.
• W2068065756 modified "2023-09-24" @default.
• W2068065756 title "Doubly excited 1 3∑−<i>g</i> state of Na2: Observation and calculation" @default.
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• W2068065756 doi "https://doi.org/10.1063/1.470349" @default.
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