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- W2068085114 abstract "Using the incoherent quasi-elastic neutron scattering (IQNS) technique, the authors have studied the molecular motions of the succinonitrile molecule N identical to C-(CH2)2-C identical to N in the plastic phase (233K<T<331K). The measurements were done using the backscattering spectrometer IN 10 of the Institut Laue-Langevin. The observed quasi-elastic spectra prove the validity of a model allowing for both motions of isomerisation between two gauche and a trans conformation and rotational motions of the molecule in its trans form from a diagonal of the BCC unit cell to another one. The correlation times found by refining this model to the data are: tau t to t(s)=1/k=(7.67+or-1.43)*10-14*exp((1762+or-44)/T(K)) for the rotational motion, and tau g to t(s)=1/k'=(1.03+or-0.40)*10-15*exp((3220+or-130)/T(K)) for the reaction of isomerisation gauche to or from trans." @default.
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- W2068085114 date "1983-09-10" @default.
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- W2068085114 title "Temperature dependence of rotational isomerisation and molecular reorientation rates in plastic succinonitrile" @default.
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- W2068085114 doi "https://doi.org/10.1088/0022-3719/16/25/006" @default.
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