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• W2068100293 abstract "Abstract Investigations on the bifunctionalization of emodin at C(6) and C(7) with respect to the synthesis of a new class of fused heterocyclic hypericin derivatives were undertaken. The synthesis of such complex anthraquinone derivatives is possible by applying a Marschalk‐type reaction with emodin‐6‐carbaldehyde as the key step. The newly synthesized pyridazinone‐fused hypericin derivative possesses a satisfying bathochromically shifted absorption maximum making it a promising candidate for further investigations concerning a possible application in photodynamic therapy. Furthermore, the herein described strategy for the bifunctionalization of emodin provides a novel route for the synthesis of anthraquinone derivatives that are difficult to obtain by other methods.(© Wiley‐VCH Verlag GmbH & Co. KGaA, 69451 Weinheim, Germany, 2006)" @default.
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• W2068100293 date "2006-02-14" @default.
• W2068100293 modified "2023-09-24" @default.
• W2068100293 title "Condensed Emodin Derivatives and Their Applicability for the Synthesis of a Fused Heterocyclic Hypericin Derivative" @default.
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• W2068100293 doi "https://doi.org/10.1002/ejoc.200500829" @default.
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