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- W2068102751 abstract "The temperature and humidity dependences of the hydration number of dodecamolybdophosphoric acid, H3Mo12PO40ṡmH2O, and dodecatungstophosphoric acid, H3W12PO40ṡnH2O, crystals are presented in the phase diagrams. The waters of crystallization of both acid crystals show a zeolitic nature, but they also show some definite hydrate in the dehydration process. The existence of the 29-, 18-, and 13-hydrate of dodecamolybdophosphoric acid and the 29-, 20-, 13-, and 6-hydrate of dodecatungstophosphoric acid is found in the range of 10–80°C and 30–95% relative humidity (RH) under an atmosphere of either oxygen or air. H3Mo12PO40ṡ29H2O is stable over 70% RH along the full range of temperatures. In comparison, H3W12PO40ṡ29H2O is stable above 20°C and over 83% RH. Other hydrates are stable under the indicated RH values. Also, the lower hydrates are stable at higher temperatures and lower RH levels. The phase diagrams of the stable ranges of these hydrates of the acid crystals were also obtained under a hydrogen atmosphere. Slight differences in these ranges are observed depending on which gas (hydrogen or either oxygen or air) is used in the atmosphere." @default.
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- W2068102751 date "1981-08-01" @default.
- W2068102751 modified "2023-10-04" @default.
- W2068102751 title "Temperature and humidity ranges of some hydrates of high-proton-conductive dodecamolybdophosphoric acid and dodecatungstophosphoric acid crystals under an atmosphere of hydrogen or either oxygen or air" @default.
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- W2068102751 doi "https://doi.org/10.1016/0167-2738(81)90111-9" @default.
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