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- W2068130995 abstract "Abstract Ethyl α-bromo-9-anthryl acetate (ABr) (I) was prepared and used in controlled-potential electrolysis at a reticulated vitreous carbon electrode, in dimethylformamide (DMF)+0.1 M Etf4NClOf4 at an applied potential of −1.1 V (vs. SCE). The most noticeable result was the formation of 9,10-anthraquinone as a result of the preparative electrolysis of I and manipulations of the electrolysed solution obtained. Several other products, each in a very low yield, and a polymer were also isolated. By using cyclic voltammetry with potential sweep rates up to 200 V s−1, it was possible to learn that the interaction of A− with ABr must be an important step in the reaction mechanism. The results are discussed in the context of recent observations on product selectivity in controlled-potential electrolysis." @default.
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- W2068130995 date "1986-02-01" @default.
- W2068130995 modified "2023-09-25" @default.
- W2068130995 title "Electroreduction of ethyl α-bromo-9-anthryl acetate and products obtained therefrom" @default.
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- W2068130995 doi "https://doi.org/10.1016/0022-0728(86)90011-2" @default.
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