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- W2068131496 abstract "The catalysis of atrazine hydrolysis at 25.0 °C by the types of acidic functional groups found in humic materials has been investigated. No evidence of catalysis by carboxylate ions was observed. From a knowledge of the types and numbers of acid functional groups in a quantitatively characterized fulvic acid, and the distributions of their K A values it was found that hydrogen ions and undissociated carboxyl groups were the only catalytic agents. The carboxyl groups have a second-order k AH of 7.88 days −1 ∙M −1 . Weakly acidic functional groups having [Formula: see text]showed no catalysis. A predictive equation has been produced for the half-life of atrazine in fulvic acid solutions at 25.0 °C. It represents a general class of equations which should permit the practical prediction of atrazine persistence in soil solutions and other natural waters. Key words: Atrazine hydrolysis, atrazine persistence, fulvic acid, fulvic acid carboxyls, acid catalysis, carboxyl catalysis" @default.
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- W2068131496 date "1985-08-01" @default.
- W2068131496 modified "2023-10-06" @default.
- W2068131496 title "ATRAZINE HYDROLYSIS IN SOILS: CATALYSIS BY THE ACIDIC FUNCTIONAL GROUPS OF FULVIC ACID" @default.
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- W2068131496 doi "https://doi.org/10.4141/cjss85-047" @default.
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