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- W2068161528 abstract "The support of a delicate reagent on a solid matrix allows for better and safer handling of the reagent itself. Because we had an interest in silicon-based supported reagents1 we turned our attention to a polymer-supported trialkylsilyl cyanide and trialkylsilyl azide starting from a commercially available trialkylsilane resin. The supported cyanide was obtained with excellent yield and proved to be shelf-stable. This supported reagent was reacted with a series of aldehydes and ketones yielding the corresponding polymer-supported cyanohydrins in good-to-excellent yields. A stability study on a model cyanohydrin demonstrated that these supported intermediates also can be stored for a prolonged time. For the last step, a cleavage strategy that could release either cyanohydrins or α-hydroxy esters was adopted. Finally, we prepared a polymer-supported trialkylsilyl azide, which also proved to be shelf-stable. © 2000 John Wiley & Sons, Inc. Biotechnol Bioeng (Comb Chem) 71:38–43, 2000." @default.
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- W2068161528 date "2000-01-01" @default.
- W2068161528 modified "2023-09-25" @default.
- W2068161528 title "Polymer-supported silyl cyanide and silyl azide: Useful reagents for solid-phase applications" @default.
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- W2068161528 doi "https://doi.org/10.1002/(sici)1097-0290(200024)71:1<38::aid-bit6>3.0.co;2-b" @default.
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