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- W2068171404 abstract "We report herein on our synthetic, structural, and catalytic investigations of new P,S-DalPhos ligands featuring pairings of phosphorus and sulfur donor groups as well as new sulfur-containing analogues of the previously reported P,N-ligands Me-DalPhos and Mor-DalPhos, featuring a 2,3-disubstituted thiophenyl backbone. In examining the catalytic performance of these new sulfur-containing ligands in the Buchwald–Hartwig amination of octylamine, aniline, or ammonia with 4-chlorotoluene, noteworthy differences in reactivity behavior relative to Me-DalPhos and Mor-DalPhos were observed." @default.
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- W2068171404 date "2015-03-01" @default.
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- W2068171404 title "Sulfur-containing DalPhos ligand variants: synthesis and application in Buchwald−Hartwig amination" @default.
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- W2068171404 doi "https://doi.org/10.1139/cjc-2014-0403" @default.
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