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- W2068176714 abstract "The electrochemical synthesis and characterization of a copolymer, poly(o-toluidine-co-o-aminophenol), were conducted using in situ piezoelectric FTIR spectroelectrochemisty. The monomer feed ratio strongly affects the copolymerization rate and the properties of the copolymer during the electrosynthesis in 0.5 M H2SO4 aqueous solution. The effects of scan rate and pH value on the electrochemical activity of the obtained copolymer were also studied. The copolymer synthesized in higher molar ratio of o-toluidine/o-aminophenol exhibited good electrical activity and stability in a broad pH range. The copolymerization mechanisms of o-toluidine and o-aminophenol were deduced. The copolymer formed through the head-to-tail coupling of the two monomers via –NH– groups was a new polymer rather than a mixture of poly(o-toluidine) and poly(o-aminophenol)." @default.
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- W2068176714 date "2010-04-01" @default.
- W2068176714 modified "2023-10-16" @default.
- W2068176714 title "Electrochemical copolymerization study of o-toluidine and o-aminophenol by the simultaneous EQCM and in situ FTIR spectroelectrochemisty" @default.
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- W2068176714 doi "https://doi.org/10.1016/j.talanta.2009.12.051" @default.
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